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Currently you are able to watch "Hart of Dixie" streaming on Freevee for free with ads or buy it as download on Amazon Video, Apple TV, Google Play Movies, Vudu, Microsoft Store.
New Yorker Zoe Hart has it all figured out - after graduating top of her class from medical school, she'll follow in her father's footsteps and become a cardio-thoracic surgeon. But when her dreams fall apart, Zoe decides to work at a small practice in Bluebell, Alabama.